Preparation and characterization of Trivalent lanthanide ion complexes with tridentate mono azo Ligand

Abstract

The lanthanide complexes of 4-(2-pyridylazo)-resorcinol are prepared in solid state. All compounds have been characterized by means of elemental analysis (C.H.N) molar conductance, magnetic susceptibility and analytical spectral studies IR and UV-Visible spectral techniques. While the complexes have additionally been characterized by differential thermal analysis data and are formulated as [Ln(C₁₁H₈N₃O₂)₃].H₂O Ln = Pr³⁺ , Nd³⁺ and Sm³⁺ ; [Ln(C₁₁H₈N₃O₂)₃] Ln = Eu³⁺, Er³⁺ and Yb³⁺ . The results of these studies on the synthesis and structural characterization, suggest neutral lanthanide complexes in which the mono azo ligand being a uninegative (deprotonated form) and tridentate ligand. The absorption spectral profiles suggest a coordination number of nine around Ln(III) ions in the complexes.